The Influence of NiO and NiOMoO catalyst for Hydrocracking of Cashew Nut Shell Liquid | Author : Lisna Efiyanti & Darma Santi | Abstract | Full Text | Abstract :Bioenergy is new and renewable alternative energy which is currently developed enthusiastically. Bioenergy could be produced by catalytic cracking method, which is cracking carbon chain to raise energy fraction. This paper observes potential non-food bioenergy of cashew nut shell liquid as an alternative bioenergy source using catalytic cracking method. The effect of impregnated-metals Nikel and Molibdenum catalyst used in hydrocracking of Cashew Nut Shell Liquid (CNSL) into temperature reaction of 450 C and ratio feed catalyst of 2 and 4. Catalysts characterization was conducted according to a gravimetric method to determine acidity of catalyst; Spectroscopy FT-IR analysis to get distribution of active site catalyst; X-Ray Diffraction (XRD) analysis to observe crystalinity of catalyst; and Gas Sorption Analyzer (GSA) to measure surface area, porosity and total of pore volume. Bioenergy of CNSL in the liquid-phase, which were predominantly by gasoline, diesel oil, and heavy oil, was further analyzed using Gas Chromatography-Mass Spectrometry (GC-MS) to determine the compound energy fraction qualitatively and quantitatively. The result showed that the NiOMoO (natural activated zeolite) provided an optimal performance with liquid product conversion was about 65-75%, and selectivity gasoline as well as diesel fraction was about 37-47% and 22-31%, respectively. |
| Natural Durability of 57 Indonesian Wood Species Tested under the Shade | Author : Jasni | Abstract | Full Text | Abstract :Natural durability of 57 wood species originated from several regions in Indonesia was investigated outdoor under coverage. Initially, wood specimens were prepared from each species with dimension of 20 cm (length), 10 cm (width) and 2.5 cm (thickness). Specimens were placed on top of the bricks to avoid direct contact with soil, arranged randomly, and covered with crated-plastic sheets which served as protecting shades. Such experiment was conducted in research forest, Cikampek, West Java. Observation was conducted one year afterwards included evaluating the percentage of deteriorated wood specimens due to wood-destroying organisms. Results showed that after a year, 57 wood species could be categorized into five classes. Further scrutiny on each class revealed that four wood species belonged to class I (very durable); 16 wood species were class II (durable), 15 wood species class III (fairly durable), three wood species class IV (non-durable), and 19 wood species were classified as class V (perishable). |
| Characteristic of Vertically Glued Laminated Bamboo Beam Made of Andong (Gigantochloa pseudoarundinacea (Steud.) Widjaja) Bamboo Strips | Author : I.M. Sulastiningsih Adi Santoso & Krisdianto | Abstract | Full Text | Abstract :The objective of the study was to determine the effect of various layer compositions on the properties of 3-layer vertically glued laminated bamboo beam (LBB). Bamboo strips for LBB fabrication were prepared from mature culms (± 4 years old) of andong bamboo (Gigantochloa pseudoarundinacea (Steud.) Widjaja) collected from private gardens in West Java. The strips were pre-treated by soaking them in 7% boron solution for four hours. Three-layer LBBs were manufactured with six different layer compositions, including bamboo combination with wood planks of manii (Maesopsis eminii Engl.) or sengon (Falcataria moluccana (Miq.) Barneby & J.W. Grimes) as the core layer. The LBB was manufactured using Water Based Polymer-Isocyanate (WBPI) adhesive. The glue spread and cold pressing time applied were 250 g/m and one hour, respectively. Results showed that the average density, moisture content, thickness swelling, and width expansion of LBB were 0.65 g/cm ; 11.1%; 2.09%; and 1.99%, respectively. No delamination occurred in all samples using WBPI adhesive, which indicates high bonding quality. The average bonding strength and percentage bamboo failure (dry test) of LBB were 61.6 kg/cm and 90%, respectively. The physical and mechanical properties of LBB were significantly affected by the layer composition. The presence of wood laminates as the core layer of LBB and the cross wide orientation of the core layer decreased mechanical properties of LBB. On the contrar y, the presence of cross-layer in LBB structure increased dimensional stability of the produced LBB.Three-layer thick laminated bamboo beam made of vertically glued andong bamboo strips with various constituted layer composition and all constitued layers laminated together in parallel grain dir ection had strength values comparable to those of class II of solid wood strength, eventhough the core layer was made of sengon or manii planks. |
| Correlation between Extractive Content and Colour Properties in Teak Heartwood | Author : Ganis Lukmandaru | Abstract | Full Text | Abstract :Beside for its high natural durability and resistancy of weather properties, teak (Tectona grandis) wood is also valued for its beautiful grain and colour. Theoretically, wood colour is highly affected by extractive content, particularly in the heartwood. Identification of correlation between wood colour and extractive content was determined through wood colour and extractive measurements on the outer part of heartwood zone. The wood samples were collected from two locations of Perum Perhutani forest plantations, i.e. KPH Randublatung (35 trees, age class III-IV) and KPH Purwakarta (32 trees, age class VI). Samples were cut from bottom part of the trees and then ground into powder measuring of 40-60 mesh. The wood colour properties(CIE-L*a*b, CIE-L*C*h, CIE-X*Y*Z, Munsell Colour Chart and ISO Brightness) were then measured. Solubility of the teak wood extractives were determined by extracting the powder in ethanol-benzene and hot water respectively. Results showed that the range of colour properties were L*= 40-62; a* = 3-0 11; b* = 19-31; C* = 20-31; h = 70-82; X= 10-25; Y= 8-23; Z=4-13; H=5-8; V =3-8; C =3-6; and W (ISO Brightness) = 4-12. Different sample location resulted in different trends of correlation between colour properties and extractive contents. No significant correlation was found between extractive solubles in hot water and colour parameters. In general, the best correlations were encountered between brightness parameters from CIE-L*a*b* or ISO with ethanolbenzene extractive contents (r=-0.54 or 0.50, respectively). |
| Utilization of Pine Wood (Pinus merkusii Jungh. & de Vriese) Smoke Liquid as Natural Latex Coagulant | Author : Santiyo Wibowo Gustan Pari & R. Esa Pangersa Gust | Abstract | Full Text | Abstract :Smoke liquid is a liquid obtained from smoke condensation during charcoal firing process. The main content of the smoke liquid is acetic acid, hence, can be used as an alter native latex coagulant. Acid in vinegar can reduce the pH of latex and cause the latex to coagulate rapidly. This paper determines effectiveness of using smoke liquid as a latex coagulant and characteristics of the treated latex. The smoke liquid in this study was derived from pine wood. The smoke liquid solutions consisted of the crude smoke liquid and the diluted solution in various concentrations of 5, 10, 15 and 20%. The smoke liquid solution was then each poured into a container of latex. Testing was undergone by observing latex coagulating time, coagulate condition, texture, color, odor and homogenity. The most effective smoke liquid which produced the best latex based on its performances was then taken for further testing of physico-chemical properties which included dry rubber content, plasticity retention index (PRI), initial plasticity (Po), final plasticity (Pa), dirt content, ash content, volatile matter content (Vm), and nitrogen content. Results were then compared with the conventional use of formic acid as a control coagulant. The result showed that the crude and distillate smoke liquid solutions with concentration of 10% produced the best coagulantperformances than the other solutions. Rubber latex treated with the crude smoke liquid produced the |
| Application of Phanerochaete chrysosporium on Biochemimechanical Pulping Process of Terentang Wood (Campnosperma auriculata Hook.f | Author : Yeni Aprianis Denny Irawati & Sri Nugroho Marsoem | Abstract | Full Text | Abstract :Terentang wood (Campnosperma auriculata Hook.f) is relatively low in specific gravity (0.3), hence its utilization as pulp by chemi-mechanical is an alternative process. Energy consumption was reduced by applying lignin degrading fungi (Phanerochaete chrysosporium) as pretreatment in the chemi-mechanical process. This paper examines the effects of P. chrysosporium incubation periods into chemical components and energy refining consumption of terentang wood. Four percent of NaOH was used in the chemi-mechanical process, and incubation periods studied were 0 (control), 3, 4 and 5 weeks. Results showed that P. chrysosporium significantly affected the weight loss, chemical properties, and refining energy consumption of terentang wood pulping process. Wood chip weight loss was about 15.95- 21.31% and alpha-cellulose raised up to 6.77%. Five weeks incubation time decreased lignin content up to 22.97% and saved the refining energy up to 22.7%. |
| The Effect of Natrium Bisulfite Addition and Ethanol Dehydration to the Quality of Porang (Amorphophallus muelleri Blume) Flour | Author : Gunawan Pasaribu Totok K. Waluyo Novitri Hastuti Gustan Pari & Emma Sahara | Abstract | Full Text | Abstract :Porang (Amorphophallus muelleri Blume) is an alternative food sources from forest. Porang grows under forest canopy and potentially developed to improve food security. Naturally harvested porang contains high oxalate and less glucomannan. This paper observes possible quality improvement of porang flour in term of whiteness and glucomannan content. Porang collected from Nganjuk, East Java was quality tested and mixed with natrium bisulfite then rinse in ethanol repetitively. Results showed that the addition of sodium bisulfite improved the whiteness of porang flour for about 6.59%. Ethanol dehydration proces was able to improve glucomannan content from 12.86% to 38.11%. Fe and Ca content of mixed porang flour showed no significant difference. Porang flour from Nganjuk contained of 1,6-Anhydro- Beta-D-Glucopyranose; 1,2,3,4-Cyclopentanetetrol,(1.alpha., 2.beta., 3.beta., 4.alpha.); cyclopropyl carbinol; aceticacid(CAS)ethylicacid; and hexadecanoic acid. |
| Anatomical Properties of Six Wood Species from Papua | Author : Andianto & R. Esa Pangersa Gusti | Abstract | Full Text | Abstract :Anatomical properties is necessary for wood species identification. This paper observes anatomical properties of six wood species originated from Papua. Wood species studied include: ketapang (Terminalia complanata K. Schum.); pala hutan (Gymnacranthera paniculata (A.DC.) Warb.); bipa (Pterygota horsfieldii (R.Br.) Kosterm).; kelumpang (Sterculia shillinglawii F. Muell.); manggis/kandis (Pentaphalangium parviflorum); and lancat/lebani (Mastixiodendron pachyclados (K. Schum) Melch.). Anatomical properties were observed according to IAWA (International Association of Wood Anatomists) checklist. The anatomical main properties observed in ketapang wood were vestured pits, prismatic crystals in non-chambered axial parenchyma cells, and druses. Pala hutan main anatomical properties were the presence of tannin tubes and oil cells which were associated with axial parenchyma. Prismatic crystals in axial parenchyma cells, and rays of two distinct sizes were two main anatomical characteristics of bipa and kelumpang wood. Prismatic crystals in chambered axial parenchyma cells was one of characteristics of manggis wood. Vestured pits and scanty paratracheal parenchyma were two main characteristics of lancat wood. For identification purposes, bipa wood could be distinguished by banded parenchyma; polygonal alternate pits; and prismatic crystals in non- chambered axial parenchyma cells. |
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